Search results for "chemistry [Arsenates]"
showing 10 items of 2372 documents
The Foundation Seamount Chain: A first survey and sampling
1997
The Foundation Seamounts form a 1400 km-long chain on the Pacific plate from 32 °S, 127 °W to the Pacific-Antarctic spreading axis at 38 °S, 111 °W. Previously only known from sparse single-beam echosoundings and satellite altimetry, we present here the first multibeam bathymetric survey and geological sampling results. We confirm that the submarine topography correlates with the altimetry, and that the chain is volcanic rather than tectonic or microcontinental in origin. The chain can be divided up morphologically and geochemically into three section: (1) west of 125 °W large flat-topped volcanoes composed of incompatible-element depleted lavas ( ≈ 1) of a near-ridge origin with little or …
The Palaeomagnetism of the Permian Rocks of the Black Forest, Germany
1972
Summary Palaeomagnetic measurements made upon Permian samples from the Black Forest, Odenwald and Pfalzerwald (excluding those measurements on samples from the Schopfheim basin) are consistent with those from north-western Europe. The virtual pole based upon 18 sites is 174.9°E. 48.4N. The measurements made on the fine-grained shales and mudstones from the Schopfheim basin are significantly different from the preceding. Since incorrect age assignment, sampling, components of secondary magnetic and tectonic effects can be excluded, the difference is attributed to incomplete removal of the effects of secular variation. The Scharfenstein massif previously regarded as Permian, was found to have…
Correlation of welded ignimbrites on Pantelleria (Strait of Sicily) using paleomagnetism
2011
Although the oldest volcanic rocks exposed at Pantelleria (Strait of Sicily) are older than 300 ka, most of the island is covered by the 45–50 ka Green Tuff ignimbrite, thought to be related to the Cinque Denti caldera, and younger lavas and scoria cones. Pre-50 ka rocks (predominantly rheomorphic ignimbrites) are exposed at isolated sea cliffs, and their stratigraphy and chronology are not completely resolved. Based on volcanic stratigraphy and K/Ar dating, it has been proposed that the older La Vecchia caldera is related to ignimbrite Q (114 ka), and that ignimbrites F, D, and Z (106, 94, and 79 ka, respectively) were erupted after caldera formation. We report here the paleomagnetic direc…
Complex-forming properties of peat humic acids from a raised bog profiles
2013
Abstract Humic substances (HS) belong to the most powerful complex-forming agents, significantly affecting major and trace element speciation in natural environment. Several authors have focused on humic–metal interactions, using differing methods and comparing humic substances on different sources. However, the intrinsic differences among the HS of different origin and the impact of humification degree on the complex formation between humic substances and metals have not received the necessary attention until now. The aim of this study is to determine the Cu(II) complexing capacity and stability constants of Cu(II) complexes of humic acids (HA) isolated from two well-characterized raised b…
Quantifying the P-T-t conditions of north-south Lhasa terrane accretion: new insight into the pre-Himalayan architecture of the Tibetan plateau
2014
An integrated field, petrological and geochronological study of the Basong Tso region of south-eastern Tibet has constrained the timing and P–T conditions of north–south Lhasa terrane accretion and provides new insight into the tectonothermal evolution of the Tibetan plateau. Two distinct high-grade metamorphic belts are recognized in the region: a southern belt (the Basong Tso complex) that consists of sheared schist and orthogneiss; and a northern belt (the Zhala complex) that comprises paragneiss and granite. Combined pseudosection modelling and U–Pb geochronology of monazite and zircon indicates that the Basong Tso complex records peak metamorphic conditions of 9 ± 0.5 kbar and 690 ± 25…
Development of topography in 3-D continental-collision models
2015
Understanding the formation and evolution of high mountain belts, such as the Himalayas and the adjacent Tibetan Plateau, has been the focus of many tectonic and numerical models. Here we employ 3-D numerical simulations to investigate the role that subduction, collision, and indentation play on lithosphere dynamics at convergent margins, and to analyze the conditions under which large topographic plateaus can form in an integrated lithospheric and upper mantle-scale model. Distinct dynamics are obtained for the oceanic subduction side (trench retreat, slab rollback) and the continental-collision side (trench advance, slab detachment, topographic uplift, lateral extrusion). We show that sla…
Subduction of the Nazca Ridge and the Inca Plateau: Insights into the formation of ore deposits in Peru
2005
A large number of ore deposits that formed in the Peruvian Andes during the Miocene (15-5 Ma) are related to the subduction of the Nazea plate beneath the South American plate. Here we show that the spatial and temporal distribution of these deposits correspond with the arrival of relatively buoyant topographic anomalies, namely the Nazca Ridge in central Peru and the now-consumed Inca Plateau in northern Peru, at the subduction zone. Plate reconstruction shows a rapid metallogenic response to the arrival of the topographic anomalies at the subduction trench. This is indicated by clusters of ore deposits situated within the proximity of the laterally migrating zones of ridge subduction. It …
Mediterranean Tertiary lamproites derived from multiple source components in postcollisional geodynamics
2008
Abstract In the Mediterranean area, lamproitic provinces in Spain, Italy, Serbia and Macedonia have uniform geological, geochemical and petrographic characteristics. Mediterranean lamproites are SiO2-rich lamproites, characterized by relatively low CaO, Al2O3 and Na2O, and high K2O/Al2O3 and Mg-number. They are enriched in LILE relative to HFSE and in Pb, and show depletion in Ti, Nb and Ta. Mediterranean lamproites show huge regional variation of Sr, Nd and 207Pb/204Pb isotopic values, with 87Sr/86Sr range of 0.707–0.722, eNd range from −13 to −3, and 207Pb/204Pb range of 15.62–15.79. Lamproitic rocks are derived from melts with three components involved in their origin, characterized by c…
The Proterozoic P–T–t Evolution of the Kemp Land Coast, East Antarctica; Constraints from Si-saturated and Si-undersaturated Metapelites
2007
Integrated metamorphic and geochronological data place new constraints on the metamorphic evolution of a Neoproterozoic orogen in east Antarctica. Granulite-facies rocks from a 150 km stretch of the Kemp Land coast reflect peak conditions involving T � 870^9908 Ca t P� 7� 4^10 kbar, with pressure increasing westward towards an Archaean craton. Electron microprobe-derived (Th þ U)^Pb monazite ages from metapelitic assemblages indicate that the major mineral textures in these rocks developed during the c. 940 Ma Rayner Orogeny. Complex compositional zoning in monazite suggests high-T recrystallization over c. 25 Myr. Diversity in metapelitic reaction textures reflects silica and ferromagnesia…
High-temperature metamorphism and crustal melting at ca. 3.2 Ga in the eastern Kaapvaal craton, southern Africa
2018
Abstract The question of whether high-grade metamorphism and crustal melting in the early Archaean were associated with modern-style plate tectonics is a major issue in unravelling early Earth crustal evolution, and the eastern Kaapvaal craton has featured prominently in this debate. We discuss a major ca. 3.2 Ga tectono-magmatic-metamorphic event in the Ancient Gneiss Complex (AGC) of Swaziland, a multiply deformed medium- to high-grade terrane in the eastern Kaapvaal craton consisting of 3.66–3.20 Ga granitoid gneisses and infolded greenstone remnants, metasedimentary assemblages and mafic dykes. We report on a 3.2 Ga granulite-facies assemblage in a metagabbro of the AGC of central Swazi…